Issue 46, 2012
From the journal:

Chemical Communications

Self-assembly of unprecedented [8 + 12] Cu-metallamacrocycle-based 3D metal–organic frameworks†

Zhouqing Xu,ab   Qiang Wang,b   Huijun Li,a   Wei Meng,a   Yi Han,a   Hongwei Hou*a  and  Yaoting Fana  

* Corresponding authors

a Department of Chemistry, Zhengzhou University, Henan 450052, P. R. China
E-mail: houhongw@zzu.edu.cn
Fax: +86-371-67761744

b Department of Physical Chemistry, Henan Polytechnic University, Henan 454000, P. R. China

Abstract

[8 + 12]-metallamacrocycle-based 3D frameworks {[Cu4(pbt)2(SO4)2(DMF)2(CH3OH)]·7H2O·DMF}n (1) and [12]-macrocycle 3D {[Cu2(pbt)(SO4)(DMSO)(CH3OH)2]·5H2O·CH3OH}n (2) have been obtained. Both complexes display antiferromagnetic couplings and high catalytic activity in the oxidative coupling reaction of 1-ethynylbenzene and oxazolidin-2-one.

Graphical abstract: Self-assembly of unprecedented [8 + 12] Cu-metallamacrocycle-based 3D metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C2CC31590D
Article type
Communication
Submitted
02 Mar 2012
Accepted
20 Apr 2012
First published
23 Apr 2012

Chem. Commun., 2012,48, 5736-5738

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Self-assembly of unprecedented [8 + 12] Cu-metallamacrocycle-based 3D metal–organic frameworks

Z. Xu, Q. Wang, H. Li, W. Meng, Y. Han, H. Hou and Y. Fan, Chem. Commun., 2012, 48, 5736 DOI: 10.1039/C2CC31590D

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