Issue 40, 2012

Enantioselective recognition by a highly ordered porphyrin-assembly on a chiral molecular gel

Abstract

Enantioselective recognition of amino acids was achieved by using a highly ordered chiral assembly of achiral porphyrin on a chiral molecular gel. Exceptionally high enantioselectivity was observed for histidine derivatives by monitoring the CD patterns and fluorescence quenching, KSV (L): 26.3 × 103 M−1; KSV(D)-enantiomer: 7.03 × 103 M−1.

Graphical abstract: Enantioselective recognition by a highly ordered porphyrin-assembly on a chiral molecular gel

Supplementary files

Article information

Article type
Communication
Submitted
15 Feb 2012
Accepted
22 Mar 2012
First published
22 Mar 2012

Chem. Commun., 2012,48, 4881-4883

Enantioselective recognition by a highly ordered porphyrin-assembly on a chiral molecular gel

H. Jintoku, M. Takafuji, R. Oda and H. Ihara, Chem. Commun., 2012, 48, 4881 DOI: 10.1039/C2CC31127E

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