Issue 36, 2012

Tandem-type Pd(ii)-catalyzed oxidative Heck reaction/intramolecular C–H amidation sequence: a novel route to 4-aryl-2-quinolinones

Abstract

A novel catalytic method for synthesizing 4-aryl-2-quinolinones is reported. The process involves two mechanistically independent, sequential Pd(II)-catalyzed reactions—the oxidative Heck reaction and the intramolecular C–H amidation—both of which smoothly proceed in the presence of a single catalytic system in a one-pot manner.

Graphical abstract: Tandem-type Pd(ii)-catalyzed oxidative Heck reaction/intramolecular C–H amidation sequence: a novel route to 4-aryl-2-quinolinones

Supplementary files

Article information

Article type
Communication
Submitted
27 Jan 2012
Accepted
07 Mar 2012
First published
08 Mar 2012

Chem. Commun., 2012,48, 4332-4334

Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C–H amidation sequence: a novel route to 4-aryl-2-quinolinones

K. Inamoto, J. Kawasaki, K. Hiroya, Y. Kondo and T. Doi, Chem. Commun., 2012, 48, 4332 DOI: 10.1039/C2CC30600J

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