Issue 41, 2012

Toward aceneporphyrinoids: synthesis and transformations of palladium(ii) meso-anthriporphyrin

Abstract

meso-Anthriporphyrin is a carbaporphyrinoid with an anthracene ring embedded in the tripyrrolic framework. The coordination of palladium(II) results in a specific intramacrocyclic metal(II)–η2-CC interaction which facilitates the cleavage to palladium(II) acyclic oligopyrrole with the appended anthracene moiety.

Graphical abstract: Toward aceneporphyrinoids: synthesis and transformations of palladium(ii) meso-anthriporphyrin

Supplementary files

Article information

Article type
Communication
Submitted
16 Jan 2012
Accepted
20 Mar 2012
First published
20 Mar 2012

Chem. Commun., 2012,48, 5004-5006

Toward aceneporphyrinoids: synthesis and transformations of palladium(II) meso-anthriporphyrin

B. Szyszko, L. Latos-Grażyński and L. Szterenberg, Chem. Commun., 2012, 48, 5004 DOI: 10.1039/C2CC30362K

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