Selective synthesis of organogold magic clusters Au54(CCPh)26

Prasenjit Maity; Tomonari Wakabayashi; Nobuyuki Ichikuni; Hironori Tsunoyama; Songhai Xie; Miho Yamauchi; Tatsuya Tsukuda

doi:10.1039/C2CC18153C

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Selective synthesis of organogold magic clusters Au₅₄(CCPh)₂₆†

Prasenjit Maity,^a Tomonari Wakabayashi,^b Nobuyuki Ichikuni,^c Hironori Tsunoyama,^a Songhai Xie,^a Miho Yamauchi^a and Tatsuya Tsukuda*^ad

Author affiliations

* Corresponding authors

^a Catalysis Research Center, Hokkaido University, Nishi 10, Kita 21, Sapporo 001-0021, Japan

^b Department of Chemistry, School of Science and Engineering, Kinki University, Higashiosaka, Osaka 577-8502, Japan

^c Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, Inage-Ku, Chiba 263-8522, Japan

^d Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: tsukuda@chem.s.u-tokyo.ac.jp
Tel: +81-3-5841-4363

Abstract

Organogold clusters Au₅₄(C₂Ph)₂₆ were selectively synthesized by reacting polymer-stabilized Au clusters (1.2 ± 0.2 nm) with excess phenylacetylene in chloroform.

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Article information

DOI: https://doi.org/10.1039/C2CC18153C
Article type: Communication
Submitted: 30 Dec 2011
Accepted: 17 Feb 2012
First published: 20 Feb 2012

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Chem. Commun., 2012,48, 6085-6087

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Selective synthesis of organogold magic clusters Au₅₄(CCPh)₂₆

P. Maity, T. Wakabayashi, N. Ichikuni, H. Tsunoyama, S. Xie, M. Yamauchi and T. Tsukuda, Chem. Commun., 2012, 48, 6085 DOI: 10.1039/C2CC18153C

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