Maximising the efficiency of continuous photo-oxidation with singlet oxygen in supercritical CO2 by use of fluorous biphasic catalysis

Jessica F. B. Hall; Xue Han; Martyn Poliakoff; Richard A. Bourne; Michael W. George

doi:10.1039/C2CC17429D

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Maximising the efficiency of continuous photo-oxidation with singlet oxygen in supercritical CO₂ by use of fluorous biphasic catalysis†

Jessica F. B. Hall,^a Xue Han,^a Martyn Poliakoff,^a Richard A. Bourne*^a and Michael W. George*^a

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* Corresponding authors

^a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: Richard.bourne@nottingham.ac.uk
Tel: +44 115 953512

Abstract

Using a continuous fluorous biphasic separation, a photo-oxidation catalyst can be recycled, with increased productivity and a ×20 fold decrease in the amount of catalyst required.

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Article information

DOI: https://doi.org/10.1039/C2CC17429D
Article type: Communication
Submitted: 28 Nov 2011
Accepted: 13 Jan 2012
First published: 17 Jan 2012

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Chem. Commun., 2012,48, 3073-3075

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Maximising the efficiency of continuous photo-oxidation with singlet oxygen in supercritical CO₂ by use of fluorous biphasic catalysis

J. F. B. Hall, X. Han, M. Poliakoff, R. A. Bourne and M. W. George, Chem. Commun., 2012, 48, 3073 DOI: 10.1039/C2CC17429D

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