Issue 23, 2012

Tandem post-synthetic modification for functionalized metal–organic frameworks viaepoxidation and subsequent epoxide ring-opening

Abstract

A sequence of two new post-synthetic modifications, epoxidation using dimethyldioxirane and subsequent epoxide ring-opening, was developed, maintaining the MOF network. A kinetic study shows that the functionalization of metal–organic frameworks with synthetically versatile and reactive oxirane groups is even possible for small pore diameters.

Graphical abstract: Tandem post-synthetic modification for functionalized metal–organic frameworks viaepoxidation and subsequent epoxide ring-opening

Supplementary files

Article information

Article type
Communication
Submitted
09 Nov 2011
Accepted
17 Jan 2012
First published
18 Jan 2012

Chem. Commun., 2012,48, 2888-2890

Tandem post-synthetic modification for functionalized metal–organic frameworks viaepoxidation and subsequent epoxide ring-opening

K. Hindelang, S. I. Vagin, C. Anger and B. Rieger, Chem. Commun., 2012, 48, 2888 DOI: 10.1039/C2CC16949E

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