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Issue 11, 2012
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Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs+-based half SOD β-cage

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Abstract

In light of ever growing interests in noncentrosymmetric materials, a fascinating reticular chemistry is illustrated via the structure of a new family of solids where the acentric symmetry of the well-known [V4+14As3+8O42Cl]5POM cluster is manifested through the network construction of counter cations featuring slabs of Cs+-based half SOD β-cages.

Graphical abstract: Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs+-based half SOD β-cage

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Publication details

The article was received on 08 Oct 2011, accepted on 11 Nov 2011 and first published on 14 Nov 2011


Article type: Communication
DOI: 10.1039/C1CC16264K
Chem. Commun., 2012,48, 1665-1667

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    Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs+-based half SOD β-cage

    W. L. Queen, J. P. West, S. Hwu, T. T. Tran, P. S. Halasyamani and D. VanDerveer, Chem. Commun., 2012, 48, 1665
    DOI: 10.1039/C1CC16264K

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