Issue 8, 2012

Catalytic reactions of chlorite with a polypyridylruthenium(ii) complex: disproportionation, chlorine dioxide formation and alcohol oxidation

Abstract

cis-[Ru(2,9-Me2phen)2(OH2)2]2+ reacts readily with chlorite at room temperature at pH 4.9 and 6.8. The ruthenium(II) complex can catalyze the disproportionation of chlorite to chlorate and chloride, the oxidation of chlorite to chlorine dioxide, as well as the oxidation of alcohols by chlorite.

Graphical abstract: Catalytic reactions of chlorite with a polypyridylruthenium(ii) complex: disproportionation, chlorine dioxide formation and alcohol oxidation

Supplementary files

Article information

Article type
Communication
Submitted
21 Sep 2011
Accepted
24 Oct 2011
First published
07 Nov 2011

Chem. Commun., 2012,48, 1102-1104

Catalytic reactions of chlorite with a polypyridylruthenium(II) complex: disproportionation, chlorine dioxide formation and alcohol oxidation

Z. Hu, H. Du, W. Man, C. Leung, H. Liang and T. Lau, Chem. Commun., 2012, 48, 1102 DOI: 10.1039/C1CC15860K

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