Quadruple-CO32− bridged octanuclear dysprosium(III) compound showing single-molecule magnet behaviour

Haiquan Tian; Lang Zhao; Yun-Nan Guo; Yang Guo; Jinkui Tang; Zhiliang Liu

doi:10.1039/C1CC15814G

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Quadruple-CO₃²⁻ bridged octanuclear dysprosium(iii) compound showing single-molecule magnet behaviour†

Haiquan Tian,^ab Lang Zhao,^a Yun-Nan Guo,^a Yang Guo,^a Jinkui Tang*^a and Zhiliang Liu^b

Author affiliations

* Corresponding authors

^a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
E-mail: tang@ciac.jl.cn
Fax: +86-431-85262878

^b College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China

Abstract

A novel octanuclear dysprosium(III) compound, templated by quadruple μ₄-CO₃²⁻ introduced via spontaneous fixation of atmospheric carbon dioxide, shows single-molecule-magnet behaviour with an obvious hysteresis loop detected by a traditional SQUID magnetometer.

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Article information

DOI: https://doi.org/10.1039/C1CC15814G
Article type: Communication
Submitted: 20 Sep 2011
Accepted: 16 Nov 2011
First published: 01 Dec 2011

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Chem. Commun., 2012,48, 708-710

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Quadruple-CO₃²⁻ bridged octanuclear dysprosium(III) compound showing single-molecule magnet behaviour

H. Tian, L. Zhao, Y. Guo, Y. Guo, J. Tang and Z. Liu, Chem. Commun., 2012, 48, 708 DOI: 10.1039/C1CC15814G

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