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Issue 6, 2012
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On the origin of the alternating Diels–Alder reactivity in [n]dendralenes

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Abstract

G4(MP2) calculations on Diels–Alder reactions of [3]- and [4]dendralene have revealed that reactant dendralene conformer populations and closed-shell singlet bis-pericyclic transition states explain their different reactivities.

Graphical abstract: On the origin of the alternating Diels–Alder reactivity in [n]dendralenes

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Publication details

The article was received on 02 Sep 2011, accepted on 29 Sep 2011 and first published on 01 Nov 2011


Article type: Communication
DOI: 10.1039/C1CC15455A
Citation: Chem. Commun., 2012,48, 832-834

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    On the origin of the alternating Diels–Alder reactivity in [n]dendralenes

    M. N. Paddon-Row and M. S. Sherburn, Chem. Commun., 2012, 48, 832
    DOI: 10.1039/C1CC15455A

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