Issue 6, 2012

“Governing initiation-supporting termination” in chiral poly(n-hexyl isocyanate)

Abstract

Poly(n-hexyl isocyanate) (PHIC) with varying molecular weights were synthesized using a chiral initiator and chiral terminator by living anionic polymerization. In such PHICs, chirality of the initiator plays a decisive role in determining the helical sense of the entire polymeric chain, whereas chirality of the terminator plays a supportive role.

Graphical abstract: “Governing initiation-supporting termination” in chiral poly(n-hexyl isocyanate)

Supplementary files

Article information

Article type
Communication
Submitted
09 Aug 2011
Accepted
05 Oct 2011
First published
21 Oct 2011

Chem. Commun., 2012,48, 826-828

“Governing initiation-supporting termination” in chiral poly(n-hexyl isocyanate)

P. N. Shah, J. Min and J. Lee, Chem. Commun., 2012, 48, 826 DOI: 10.1039/C1CC14927J

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