Issue 10, 2012
From the journal:

Chemical Communications

A modular system for regeneration of NADcofactors using graphite particles modified with hydrogenase and diaphorase moieties†‡

Holly A. Reeve,a   Lars Lauterbach,b   Philip A. Ash,a   Oliver Lenzb  and  Kylie A. Vincent*a  

* Corresponding authors

a Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, UK
E-mail: kylie.vincent@chem.ox.ac.uk
Fax: +44 1865 272690
Tel: +44 1865 282611

b Humboldt-Universität zu Berlin, Institut für Biologie/Mikrobiologie, Chausseestraße 117, 10115, Berlin, Germany
E-mail: oliver.lenz@rz.hu-berlin.de

Abstract

Pyrolytic graphite particles modified with hydrogenase and an NAD+/NADH cycling enzyme provide a modular heterogeneous catalyst system for regeneration of oxidised or reduced nicotinamide cofactors using H2 and H+ as electron source or sink. Particles can be tuned for cofactor supply under different conditions by appropriate choice of hydrogenase.

Graphical abstract: A modular system for regeneration of NAD cofactors using graphite particles modified with hydrogenase and diaphorase moieties

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Article information

DOI
https://doi.org/10.1039/C1CC14826E
Article type
Communication
Submitted
04 Aug 2011
Accepted
21 Sep 2011
First published
10 Oct 2011

Chem. Commun., 2012,48, 1589-1591

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A modular system for regeneration of NAD cofactors using graphite particles modified with hydrogenase and diaphorase moieties

H. A. Reeve, L. Lauterbach, P. A. Ash, O. Lenz and K. A. Vincent, Chem. Commun., 2012, 48, 1589 DOI: 10.1039/C1CC14826E

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