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Issue 4, 2011
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Gold(i)-catalyzed intermolecular (4 + 2) cycloaddition of allenamides and acyclic dienes

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Abstract

A new type of intermolecular (4 + 2) cycloaddition, based on a gold-catalyzed reaction between allenamides and acyclic conjugated dienes, is reported. The annulation, which fails under standard Diels–Alder conditions, provides a straight entry to a variety of differently substituted cyclohexenes, and takes place with excellent regio- and diastereoselectivity.

Graphical abstract: Gold(i)-catalyzed intermolecular (4 + 2) cycloaddition of allenamides and acyclic dienes

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Supplementary files

Article information


Submitted
15 Dec 2010
Accepted
13 Jan 2011
First published
14 Feb 2011

Chem. Sci., 2011,2, 633-637
Article type
Edge Article

Gold(I)-catalyzed intermolecular (4 + 2) cycloaddition of allenamides and acyclic dienes

H. Faustino, F. López, L. Castedo and J. L. Mascareñas, Chem. Sci., 2011, 2, 633
DOI: 10.1039/C0SC00630K

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