Issue 4, 2011
From the journal:

Chemical Science

Amino olefin nickel(i) and nickel(0) complexes as dehydrogenationcatalysts for amineboranes†‡

Matthias Vogt,a   Bas de Bruin,b   Heinz Berke,c   Mónica Trincado*a  and  Hansjörg Grützmacher*a  

* Corresponding authors

a Department of Chemistry and Applied Biosciences, ETH, Hönggerberg, Zürich, Switzerland
E-mail: gruetzmacher@inorg.chem.ethz.ch
Web: http://www.gruetzmacher.ethz.ch

b Universiteit van Amsterdam, Van’t Hoff Institute for Molecular Sciences, Science Park 904, Amsterdam, The Netherlands

c Universität Zürich, Anorganisch-chemisches Institut, Zürich, Switzerland

Abstract

A rare paramagnetic organometallic nickel(I) olefin complex can be isolated using the ligand bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine. This complex and related nickel(0) hydride complexes show very high catalytic activity in the dehydrogenation of dimethylamino borane with release of one equivalent of dihydrogen.

Graphical abstract: Amino olefin nickel(i) and nickel(0) complexes as dehydrogenation catalysts for amine boranes

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Article information

DOI
https://doi.org/10.1039/C0SC00483A
Article type
Edge Article
Submitted
12 Sep 2010
Accepted
17 Dec 2010
First published
17 Jan 2011

Chem. Sci., 2011,2, 723-727

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Amino olefin nickel(I) and nickel(0) complexes as dehydrogenation catalysts for amine boranes

M. Vogt, B. de Bruin, H. Berke, M. Trincado and H. Grützmacher, Chem. Sci., 2011, 2, 723 DOI: 10.1039/C0SC00483A

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