Issue 3, 2011
From the journal:

Chemical Science

Vinylogous reactivity of silver(i) vinylcarbenoids†

Jørn H. Hansena  and  Huw M. L. Davies*a  

* Corresponding authors

a Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, USA
E-mail: hmdavie@emory.edu
Fax: +1 404-727-7766
Tel: +1 404-727-6839

Abstract

Silver(I)-catalyzed reactions of vinyldiazoacetates have been shown to involve the intermediacy of silver-carbenoid species. The silver vinylcarbenoid displays a strong preference for electrophilic reactivity at the vinyl terminus in O–H insertion reactions.

Graphical abstract: Vinylogous reactivity of silver(i) vinylcarbenoids

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Article information

DOI
https://doi.org/10.1039/C0SC00422G
Article type
Edge Article
Submitted
09 Aug 2010
Accepted
06 Oct 2010
First published
22 Nov 2010

Chem. Sci., 2011,2, 457-461

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Vinylogous reactivity of silver(I) vinylcarbenoids

J. H. Hansen and H. M. L. Davies, Chem. Sci., 2011, 2, 457 DOI: 10.1039/C0SC00422G

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