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Issue 1, 2011
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Formation of nanoporous materials via mild retro-Diels–Alder chemistry

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Abstract

Poly(styrene)-block-poly(ethylene oxide) copolymers synthesized via the combination of reversible addition fragmentation chain transfer (RAFT) polymerization and hetero Diels–Alder (HDA) cycloaddition can be cleaved in the solid state by a retro-HDA reaction occurring at 90 °C. Nanoporous films can be prepared from these polymers using a simple heating and washing procedure.

Graphical abstract: Formation of nanoporous materials via mild retro-Diels–Alder chemistry

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Article information


Submitted
18 Aug 2010
Accepted
17 Sep 2010
First published
04 Oct 2010

Polym. Chem., 2011,2, 83-87
Article type
Communication

Formation of nanoporous materials via mild retro-Diels–Alder chemistry

M. Glassner, J. P. Blinco and C. Barner-Kowollik, Polym. Chem., 2011, 2, 83
DOI: 10.1039/C0PY00267D

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