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Issue 16, 2011
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Synthesis of the proposed structure of phaeosphaeride A

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Abstract

The first total synthesis of the proposed structure of phaeosphaeride A has been achieved via six-membered-ring formation by means of an intramolecular vinyl-anion aldol reaction as the key step. This synthesis suggests a revised configurational assignment for phaeosphaeride A.

Graphical abstract: Synthesis of the proposed structure of phaeosphaeride A

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Publication details

The article was received on 16 Apr 2011, accepted on 19 May 2011 and first published on 19 May 2011


Article type: Paper
DOI: 10.1039/C1OB05612C
Citation: Org. Biomol. Chem., 2011,9, 5825-5832

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    Synthesis of the proposed structure of phaeosphaeride A

    K. Kobayashi, I. Okamoto, N. Morita, T. Kiyotani and O. Tamura, Org. Biomol. Chem., 2011, 9, 5825
    DOI: 10.1039/C1OB05612C

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