Issue 17, 2011
From the journal:

Organic & Biomolecular Chemistry

Synthesis of a [2]rotaxane operated in basic environment†

Wenlong Yang,ab   Yongjun Li,*a   Jianhong Zhang,ab   Yanwen Yu,ab   Taifeng Liu,ab   Huibiao Liua  and  Yuliang Li*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, P.R. China
E-mail: ylli@iccas.ac.cn, liyj@iccas.ac.cn
Fax: (+) 86-10-82616576
Tel: (+) 86-10-62588934

b Graduate University of Chinese Academy of Sciences, Beijing, P.R. China

Abstract

A tight [2]rotaxane with two chromophores as stoppers is described, in which the macrocycle is able to reversibly move by tuning of base. This moving process can result in intramolecular photo-induced electron transfer (PET), changing the photo-physical properties.

Graphical abstract: Synthesis of a [2]rotaxane operated in basic environment

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Article information

DOI
https://doi.org/10.1039/C1OB05726J
Article type
Paper
Submitted
09 May 2011
Accepted
06 Jun 2011
First published
07 Jun 2011

Org. Biomol. Chem., 2011,9, 6022-6026

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Synthesis of a [2]rotaxane operated in basic environment

W. Yang, Y. Li, J. Zhang, Y. Yu, T. Liu, H. Liu and Y. Li, Org. Biomol. Chem., 2011, 9, 6022 DOI: 10.1039/C1OB05726J

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