Issue 10, 2011
From the journal:

Organic & Biomolecular Chemistry

Changing the volume of a giant macrocycle: the swelling of the macrocycle with organic solvents†‡

Aya Harano,ab   Minako Tanaka,ab   Takeshi Nakagaki,ab   Masahiko Annaka,b   Keiko Ideta,c   Kenta Gotoa  and  Teruo Shinmyozu*a  

* Corresponding authors

a Institute for Materials Chemistry and Engineering (IMCE), Kyushu University, Hakozaki 6-10-1, Higashi-ku, Fukuoka 812-8581, Japan
E-mail: shinmyo@ms.ifoc.kyushu-u.ac.jp

b Department of Chemistry, Graduate School of Sciences, Kyushu University, Hakozaki 6-10-1, Higashi-ku, Fukuoka 812-8581, Japan

c Institute for Materials Chemistry and Engineering (IMCE), Kyushu University, 6-1 Kasuga-koh-en, Kasuga 816-8580, Japan

Abstract

The novel tetrahedral macrocycles 1a–1c have been synthesized. Macrocycles 1a and 1c were revealed to have the property to increase in volume in solution by complexation between the macrocycle and the solvent molecules.

Graphical abstract: Changing the volume of a giant macrocycle: the swelling of the macrocycle with organic solvents

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Article information

DOI
https://doi.org/10.1039/C1OB05272A
Article type
Communication
Submitted
19 Feb 2011
Accepted
22 Mar 2011
First published
22 Mar 2011

Org. Biomol. Chem., 2011,9, 3611-3614

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Changing the volume of a giant macrocycle: the swelling of the macrocycle with organic solvents

A. Harano, M. Tanaka, T. Nakagaki, M. Annaka, K. Ideta, K. Goto and T. Shinmyozu, Org. Biomol. Chem., 2011, 9, 3611 DOI: 10.1039/C1OB05272A

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