Issue 3, 2011
From the journal:

Organic & Biomolecular Chemistry

Synthesis of thioethers via metal-free reductive coupling of tosylhydrazones with thiols†

Qiuping Ding,*ab   Banpeng Cao,a   Jianjun Yuan,a   Xianjin Liua  and  Yiyuan Peng*ab  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Jiangxi Normal University, 99 Ziyang Road, Nanchang, China
E-mail: dqpjxnu@gmail.com

b Key Laboratory of Green Chemistry of Jiangxi Province, 99 Ziyang Road, Nanchang, China

Abstract

A metal-free procedure for the synthesis of thioethers is described via the base-promoted reductive coupling of tosylhydrazones with thiols through an insertion of a carbene into the S–H bond.

Graphical abstract: Synthesis of thioethers via metal-free reductive coupling of tosylhydrazones with thiols

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Article information

DOI
https://doi.org/10.1039/C0OB00639D
Article type
Paper
Submitted
28 Aug 2010
Accepted
07 Oct 2010
First published
17 Nov 2010

Org. Biomol. Chem., 2011,9, 748-751

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Synthesis of thioethers via metal-free reductive coupling of tosylhydrazones with thiols

Q. Ding, B. Cao, J. Yuan, X. Liu and Y. Peng, Org. Biomol. Chem., 2011, 9, 748 DOI: 10.1039/C0OB00639D

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