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Issue 44, 2011
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Experimental and computational approach of understanding the gas adsorption in amino functionalized interpenetrated metal organic frameworks (MOFs)

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Abstract

Two isostructural, three dimensional, interpenetrated, amino (–NH2) functionalized Metal Organic Frameworks [Cd(ANIC)2] (Cd-ANIC-1) and [Co(ANIC)2] (Co-ANIC-1) with amine-lined pores have been reported. The framework adopts dia topology with interpenetration. Cd-ANIC-1 and Co-ANIC-1 show high CO2 (273 K) and H2 (77 K) uptake due to the presence of free –NH2 groups and framework interpenetration. The effect of interpenetration and amino functionalization on gas uptake properties of MOFs has been analysed experimentally and computationally, in the isostructural MOFs Cd-ANIC-1 and Co-ANIC-1.

Graphical abstract: Experimental and computational approach of understanding the gas adsorption in amino functionalized interpenetrated metal organic frameworks (MOFs)

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Publication details

The article was received on 05 Aug 2011, accepted on 02 Sep 2011 and first published on 06 Oct 2011


Article type: Paper
DOI: 10.1039/C1JM13762J
J. Mater. Chem., 2011,21, 17737-17745

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    Experimental and computational approach of understanding the gas adsorption in amino functionalized interpenetrated metal organic frameworks (MOFs)

    P. Pachfule, Y. Chen, J. Jiang and R. Banerjee, J. Mater. Chem., 2011, 21, 17737
    DOI: 10.1039/C1JM13762J

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