Visual detection of copper ions based on azide- and alkyne-functionalized polydiacetylene vesicles

Abstract

A new method for visual detection of Cu²⁺ based on azide- and alkyne-functionalized polydiacetylene (PDA-aa) vesicles has been developed. In the presence of ascorbic acid, Cu²⁺ can be reduced to Cu⁺ and catalyze the click reaction between the two functional groups. After incubation with Cu²⁺ and ascorbic acid, a PDA-aa solution changed its color from blue to red, which was attributed to conformational transition of the conjugated backbone. Other metal ions were explored but only induced negligible color changes. This method provides a naked eye detection of Cu²⁺ in water without the aid of complex instruments.