New hybrid nanocomposites containing carbon nanotubes, inorganic fullerene-like WS2nanoparticles and poly(ether ether ketone) (PEEK)

Abstract

Single-walled carbon nanotubes (SWCNTs) and inorganic fullerene-like WS₂ nanoparticles were successfully dispersed in poly(ether ether ketone) (PEEK) by advantageously traditional melt processing techniques. This strategy offers an attractive way to combine the merits of organic and inorganic materials into novel hybrid systems that challenge emerging polymer/CNT nanocomposites in terms of performance, cost and processability. In particular, the incorporation of IF-WS₂ has shown to be efficient to produce well-dispersed PEEK/SWCNT composites influenced in turn by the processing method. The morphology, thermal stability, crystallization behaviour, thermal conductivity as well as mechanical and electrical properties of PEEK/SWCNT composites were tuneable by the introduction of small amounts of IF-WS₂. The overall structural, thermal, mechanical and electrical performances confirm the potential use of SWCNTs and IF-WS₂ for the preparation of advanced hybrid nanocomposites as lightweight alternatives for use in critical industrial applications of high-performance and high-temperature thermoplastics like PEEK.