The existence of a complex and highly frustrated mesophase, namely the twist grain boundary (TGB) phase possessing chiral smectic C (SmC*) blocks, denoted as the TGBC* phase, over an exceptionally wide (105–150 °C) thermal range in chiral dimers has been evidenced by optical, calorimetric, spectroscopic, X-ray and He–Ne laser diffraction studies.
U. S. Hiremath, G. M. Sonar, D. S. S. Rao and C. V. Yelamaggad, J. Mater. Chem., 2011, 21, 4064 DOI: 10.1039/C0JM04547K
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