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Issue 8, 2011
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Recyclable enamine catalysts for asymmetric direct cross-aldol reaction of aldehydes in emulsion media

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Abstract

Highly diastereo- and enantioselective cross-aldol reactions of aldehydes (>20 : 1 dr, 99% ee), catalyzed by chiral diamine-polyoxometalate acid combined enamine catalysts in emulsion media, are reported. This type of catalysts can be recycled several times without significant deterioration of activity and selectivity.

Graphical abstract: Recyclable enamine catalysts for asymmetric direct cross-aldol reaction of aldehydes in emulsion media

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Publication details

The article was received on 28 Apr 2011, accepted on 31 May 2011 and first published on 05 Jul 2011


Article type: Communication
DOI: 10.1039/C1GC15473G
Citation: Green Chem., 2011,13, 1983-1985
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    Recyclable enamine catalysts for asymmetric direct cross-aldol reaction of aldehydes in emulsion media

    Q. Gao, Y. Liu, S. Lu, J. Li and C. Li, Green Chem., 2011, 13, 1983
    DOI: 10.1039/C1GC15473G

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