Issue 7, 2011
From the journal:

Green Chemistry

Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation

Yongbo Kuang,a   Yuta Nabae,a   Teruaki Hayakawaa  and  Masa-aki Kakimoto*a  

* Corresponding authors

a Department of Organic and Polymeric Materials, Tokyo Institute of Technology, Meguro-ku, Tokyo, Japan
E-mail: mkakimot@o.cc.titech.ac.jp.ccc
Fax: +81 3-5734-2875
Tel: +81 3-5734-2433

Abstract

An expedient, non-metallic green protocol for aerobic oxidation of alcohols was established. 1-Methyl-2-azaadamantane N-oxyl was used as the core catalyst due to its superior chemical stability and catalytic performance. The catalyst can be easily reused through phase separation by taking advantage of its solubility feature, which varies with its oxidation state.

Graphical abstract: Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation

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Article information

DOI
https://doi.org/10.1039/C1GC15076F
Article type
Communication
Submitted
20 Jan 2011
Accepted
06 Apr 2011
First published
26 Apr 2011

Green Chem., 2011,13, 1659-1663

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Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation

Y. Kuang, Y. Nabae, T. Hayakawa and M. Kakimoto, Green Chem., 2011, 13, 1659 DOI: 10.1039/C1GC15076F

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