Issue 5, 2011
From the journal:

Green Chemistry

Regioselective functionalization of glycerol with a dithiocarbamate moiety: an environmentally friendly route to safer fungicides†

Rodolphe De Sousa,a   Cyril Thurier,b   Christophe Len,bc   Yannick Pouilloux,a   Joël Barraulta  and  François Jérôme*a  

* Corresponding authors

a Laboratoire de Catalyse en Chimie Organique, Université de Poitiers-CNRS, 40 Avenue du recteur Pineau, Poitiers Cedex, France
E-mail: francois.jerome@univ-poitiers.fr
Fax: +33 5 49 45 33 49
Tel: +33 5 49 45 40 52

b Université de Poitiers, UMR 6514 CNRS, 40 avenue du Recteur Pineau, Poitiers cedex, France

c Université de Technologie de Compiègne, Ecole Supérieure de Chimie Organique et Minérale, 1 allée du Réseau Jean-Marie Buckmaster, Compiègne, France

Abstract

We report here a convenient pathway for the direct functionalization of glycerol with a dithiocarbamate moiety. This work opens up a cost-efficient and environmentally friendly route to safer fungicides. It should be noted that whereas functionalization of glycerol usually suffers from a lack of selectivity, we show here that our process is fully regioselective.

Graphical abstract: Regioselective functionalization of glycerol with a dithiocarbamate moiety: an environmentally friendly route to safer fungicides

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Article information

DOI
https://doi.org/10.1039/C1GC15053G
Article type
Communication
Submitted
14 Jan 2011
Accepted
11 Mar 2011
First published
28 Mar 2011

Green Chem., 2011,13, 1129-1132

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Regioselective functionalization of glycerol with a dithiocarbamate moiety: an environmentally friendly route to safer fungicides

R. De Sousa, C. Thurier, C. Len, Y. Pouilloux, J. Barrault and F. Jérôme, Green Chem., 2011, 13, 1129 DOI: 10.1039/C1GC15053G

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