Issue 6, 2011
From the journal:

Green Chemistry

An efficient and heterogeneous recyclable palladiumcatalyst for chemoselective conjugate reduction of α,β-unsaturated carbonyls in aqueous medium†

Dattatraya B. Bagal,a   Ziyauddin S. Qureshi,a   Kishor P. Dhake,a   Shoeb R. Khana  and  Bhalchandra M. Bhanage*a  

* Corresponding authors

a Department of Chemistry, Institute of Chemical Technology (Autonomous), Matunga, Mumbai, India
E-mail: bhalchandra_bhanage@yahoo.com, bm.bhanage@ictmumbai.edu.in
Fax: +91 22 2414 5614
Tel: +91 22 3361 1111/2222

Abstract

An highly efficient PS-Pd-NHC catalytic system has been developed for chemoselective conjugate reduction of α,β-unsaturated carbonyl compounds providing good to excellent conversion with remarkable chemoselectivity (up to 100%). The developed protocol is more advantageous due to use of HCOONa as hydrogen source, environmentally benign water as solvent and effective catalyst recyclability.

Graphical abstract: An efficient and heterogeneous recyclable palladium catalyst for chemoselective conjugate reduction of α,β-unsaturated carbonyls in aqueous medium

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Article information

DOI
https://doi.org/10.1039/C1GC15050B
Article type
Communication
Submitted
14 Jan 2011
Accepted
28 Mar 2011
First published
13 Apr 2011

Green Chem., 2011,13, 1490-1494

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An efficient and heterogeneous recyclable palladium catalyst for chemoselective conjugate reduction of α,β-unsaturated carbonyls in aqueous medium

D. B. Bagal, Z. S. Qureshi, K. P. Dhake, S. R. Khan and B. M. Bhanage, Green Chem., 2011, 13, 1490 DOI: 10.1039/C1GC15050B

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