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Volume 152, 2011
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Oxidative coupling of alcohols on gold: Insights from experiments and theory

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Abstract

Molecular level understanding of the mechanism of oxidative coupling of alcohols on metallic Au(111) activated by oxygen is achieved through a combination of experiments and theoretical calculations. The facility of the β–H elimination of the alkoxys, which increases with the length of the alkyl chain, is identified to be critical in determining the product distributions. Dioxymethylene serves as a formaldehyde reservoir in the cross-coupling reaction between methanol and formaldehyde through its reversible formation and decomposition, contributing to the high selectivity for the coupling products.

  • This article is part of the themed collection: Gold
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Publication details

The article was received on 10 Feb 2011, accepted on 22 Mar 2011 and first published on 10 Aug 2011


Article type: Paper
DOI: 10.1039/C1FD00015B
Faraday Discuss., 2011,152, 307-320

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    Oxidative coupling of alcohols on gold: Insights from experiments and theory

    B. Xu and C. M. Friend, Faraday Discuss., 2011, 152, 307
    DOI: 10.1039/C1FD00015B

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