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Issue 9, 2011
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Low-temperature phase of Li2FeSiO4: crystal structure and a preliminary study of electrochemical behavior

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Abstract

A nearly single-phase of a low-temperature (LT) phase of Li2FeSiO4 is prepared by a hydrothermal method at 150 °C. We report the detailed crystal structure of LT-Li2FeSiO4 (S.G. Pmn21) by applying Rietveld/MEM analysis to the synchrotron XRD pattern. LT-Li2FeSiO4 shows 150 mA h g−1 as the positive electrode materials of rechargeable batteries.

Graphical abstract: Low-temperature phase of Li2FeSiO4: crystal structure and a preliminary study of electrochemical behavior

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Supplementary files

Article information


Submitted
03 Nov 2010
Accepted
30 Nov 2010
First published
04 Jan 2011

Dalton Trans., 2011,40, 1846-1848
Article type
Communication

Low-temperature phase of Li2FeSiO4: crystal structure and a preliminary study of electrochemical behavior

N. Yabuuchi, Y. Yamakawa, K. Yoshii and S. Komaba, Dalton Trans., 2011, 40, 1846
DOI: 10.1039/C0DT01523G

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