Issue 47, 2011
From the journal:

Dalton Transactions

Linear chain aluminium(iii) carboxymethylphosphonate with encapsulated ammonium ions†

Ayi Anyama Ayi,ab   Tiffany L. Kinnibrugha  and  Abraham Clearfield*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, Texas, USA
E-mail: clearfield@chem.tamu.edu
Fax: (979)845-2370
Tel: (979)845-2936

b Department of Pure and Applied Chemistry, University of Calabar, P.M.B. 1115, Calabar, Nigeria
E-mail: ayiayi72@gmail.com
Tel: +2348035961521

Abstract

An aluminium carboxymethylphosphonate of composition (NH4)2Al(H1/2O3PCH2CO2)2 has been prepared hydrothermally. The aluminium cation is chelated by six membered rings formed from bonding by both the carboxylate and phosphonate oxygens. These chelate rings in turn form larger eight membered rings by connecting to similar chelate groups to form chains running along the a-axis.

Graphical abstract: Linear chain aluminium(iii) carboxymethylphosphonate with encapsulated ammonium ions

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Article information

DOI
https://doi.org/10.1039/C1DT11620G
Article type
Communication
Submitted
27 Aug 2011
Accepted
04 Oct 2011
First published
27 Oct 2011

Dalton Trans., 2011,40, 12648-12650

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Linear chain aluminium(III) carboxymethylphosphonate with encapsulated ammonium ions

A. A. Ayi, T. L. Kinnibrugh and A. Clearfield, Dalton Trans., 2011, 40, 12648 DOI: 10.1039/C1DT11620G

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