Issue 39, 2011
From the journal:

Dalton Transactions

Chiral salen-metal derivatives of polyoxometalates with asymmetric catalytic and photocatalytic activities†

Xing Meng,a   Chao Qin,a   Xin-Long Wang,*a   Zhong-Min Su,*a   Bo Lib  and  Qi-Hua Yang*b  

* Corresponding authors

a Institute of Functional Materials, Department of Chemistry, Key Laboratory of Polyoxometalates Science of Ministry of Education, Northeast Normal University, Changchun, China
E-mail: zmsu@nenu.edu.cn

b State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China
E-mail: yangqh@dicp.ac.cn

Abstract

Immobilization of the chiral salen-metal complex [MnIII(salen)(H2O)2ClO4] on the Keggin-type polyoxometalate (POM) skeletons leads to the isolation of POM derivatives functionalized with chiral salen-metal complexes, which represent the first examples of introducing chiral salen-metal complexes into the POM systems.

Graphical abstract: Chiral salen-metal derivatives of polyoxometalates with asymmetric catalytic and photocatalytic activities

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Article information

DOI
https://doi.org/10.1039/C1DT11227A
Article type
Communication
Submitted
28 Jun 2011
Accepted
17 Aug 2011
First published
09 Sep 2011

Dalton Trans., 2011,40, 9964-9966

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Chiral salen-metal derivatives of polyoxometalates with asymmetric catalytic and photocatalytic activities

X. Meng, C. Qin, X. Wang, Z. Su, B. Li and Q. Yang, Dalton Trans., 2011, 40, 9964 DOI: 10.1039/C1DT11227A

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