Issue 45, 2011
From the journal:

Dalton Transactions

p-tert-Butylcalix[8]arene: A support for sodium and sodium-manganese clusters that exhibit interesting self-assembly properties†

Ruaraidh D. McIntosh,a   Stephanie M. Taylor,b   Sergio Sanz,b   Christine M. Beavers,c   Simon J. Teat,c   Euan K. Brechin*b  and  Scott J. Dalgarno*a  

* Corresponding authors

a School of Engineering and Physical Sciences – Chemistry, Heriot-Watt University, Riccarton, Edinburgh, Scotland
E-mail: S.J.Dalgarno@hw.ac.uk
Fax: +44(0) 131 451 3180
Tel: +44 (0)131 451 8025

b EaStCHEM School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, Scotland
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: +44 (0)131 650 6453
Tel: +44 (0)131 650 7545

c Advanced Light Source, Berkeley Laboratory, 1 Cyclotron Road, MS6R2100, Berkeley, California, USA

Abstract

A series of new sodium and mixed sodium/manganese clusters have been formed using p-tert-butylcalix[8]arene as a support. In all cases the calixarene adopts the pleated-loop conformation, and the resulting complexes show interesting self-assembly properties depending on the ligated solvent molecules around individual cluster cores.

Graphical abstract: p-tert-Butylcalix[8]arene: A support for sodium and sodium-manganese clusters that exhibit interesting self-assembly properties

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Article information

DOI
https://doi.org/10.1039/C1DT10821B
Article type
Paper
Submitted
03 May 2011
Accepted
02 Aug 2011
First published
28 Sep 2011

Dalton Trans., 2011,40, 12265-12270

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p-tert-Butylcalix[8]arene: A support for sodium and sodium-manganese clusters that exhibit interesting self-assembly properties

R. D. McIntosh, S. M. Taylor, S. Sanz, C. M. Beavers, S. J. Teat, E. K. Brechin and S. J. Dalgarno, Dalton Trans., 2011, 40, 12265 DOI: 10.1039/C1DT10821B

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