Issue 34, 2011
From the journal:

Dalton Transactions

Mechanochromism of Agi complexes with iPrNHC(S)NHP(S)(OiPr)2†

Maria G. Babashkina,*a   Damir A. Safin,a   Michael Bolteb  and  Yann Garciaa  

* Corresponding authors

a Institute of Condensed Matter and Nanosciences, Université Catholique de Louvain, MOST – Inorganic Chemistry, Place L. Pasteur 1, Belgium
E-mail: maria.babashkina@ksu.ru
Fax: +32(0) 1047 2330
Tel: +32(0) 1047 2831

b Institut für Anorganische Chemie J.-W.-Goethe-Universität, Frankfurt/Main, Germany

Abstract

Reaction of the potassium salt of iPrNHC(S)NHP(S)(OiPr)2 (HL) with AgPF6 leads to the hexanuclear [{Ag3(iPrNHC(S)NP(S)(OiPr)2-S,S′)3}2] ([(Ag3L3)2]) complex. The reversible conversion between yellow-emitting ([(Ag3L3)2]) and blue-emitting ([Ag3L3]) materials on grinding and recrystallization was established. [Ag3L3] was also prepared by a mechanically induced solid-state reaction.

Graphical abstract: Mechanochromism of Agi complexes with iPrNHC(S)NHP(S)(OiPr)2

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Article information

DOI
https://doi.org/10.1039/C1DT10688K
Article type
Communication
Submitted
17 Apr 2011
Accepted
25 May 2011
First published
15 Jun 2011

Dalton Trans., 2011,40, 8523-8526

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Mechanochromism of AgI complexes with iPrNHC(S)NHP(S)(OiPr)2

M. G. Babashkina, D. A. Safin, M. Bolte and Y. Garcia, Dalton Trans., 2011, 40, 8523 DOI: 10.1039/C1DT10688K

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