Issue 35, 2011
From the journal:

Dalton Transactions

Pd, Pt, and Ru complexes of a pincer bis(amino)amide ligand†

Peng Ren,a   Oleg Vechorkin,a   Zsolt Csok,a   Isuf Salihu,a   Rosario Scopellitia  and  Xile Hu*a  

* Corresponding authors

a Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), ISIC-LSCI, BCH 3305, Lausanne, Switzerland
E-mail: xile.hu@epfl.ch
Fax: +41 21 6939305
Tel: +41 21 6939781

Abstract

An improved synthesis of pincer ligand bis[(2-dimethylamino)phenyl]amine (MeN2NH) was reported. Reaction of the Li complex of MeN2N with suitable Pd, Pt, and Ru precursors gave the corresponding metal complexes. The structures of the Pd, Pt, and Ru complexes were determined. The Ru complex showed activity in catalytic transfer hydrogenation of aryl and alkyl ketones.

Graphical abstract: Pd, Pt, and Ru complexes of a pincer bis(amino)amide ligand

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Article information

DOI
https://doi.org/10.1039/C1DT10195A
Article type
Paper
Submitted
03 Feb 2011
Accepted
24 Feb 2011
First published
15 Mar 2011

Dalton Trans., 2011,40, 8906-8911

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Pd, Pt, and Ru complexes of a pincer bis(amino)amide ligand

P. Ren, O. Vechorkin, Z. Csok, I. Salihu, R. Scopelliti and X. Hu, Dalton Trans., 2011, 40, 8906 DOI: 10.1039/C1DT10195A

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