Formation and characterization of a six-coordinate iron(iii) complex with the most ruffled porphyrin ring†
Abstract
The six-coordinate iron(III) porphyrin complex, [Fe(TiPrP)(2-MeBzIm)2]+, having the most ruffled porphyrin ring shows some unusual properties; the complex adopts the pure (dxz, dyz)4(dxy)1 ground state below 200 K in spite of the coordination of an