Issue 14, 2011
From the journal:

Dalton Transactions

Formation and characterization of a six-coordinate iron(iii) complex with the most ruffled porphyrin ring†

Akira Ikezakiab  and  Mikio Nakamura*abc  

* Corresponding authors

a Department of Chemistry, School of Medicine, Toho University, Ota-ku, Tokyo, Japan
E-mail: mnakamu@med.toho-u.ac.jp

b Research Center of Materials with Integrated Properties, Toho University, Funabashi, Japan

c Division of Chemistry, Graduate School of Science, Toho University, Funabashi, Japan

Abstract

The six-coordinate iron(III) porphyrin complex, [Fe(TiPrP)(2-MeBzIm)2]+, having the most ruffled porphyrin ring shows some unusual properties; the complex adopts the pure (dxz, dyz)4(dxy)1 ground state below 200 K in spite of the coordination of an imidazole ligand and exhibits the rare spin transition to the (dxz, dyz)3(dxy)1(dz2)1 state at higher temperature.

Graphical abstract: Formation and characterization of a six-coordinate iron(iii) complex with the most ruffled porphyrin ring

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Article information

DOI
https://doi.org/10.1039/C1DT10042D
Article type
Communication
Submitted
30 Dec 2010
Accepted
08 Feb 2011
First published
04 Mar 2011

Dalton Trans., 2011,40, 3455-3458

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Formation and characterization of a six-coordinate iron(III) complex with the most ruffled porphyrin ring

A. Ikezaki and M. Nakamura, Dalton Trans., 2011, 40, 3455 DOI: 10.1039/C1DT10042D

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