O–O Bond activation in H2O2 and (CH3)3C-OOH mediated by [Ni(cyclam)(CH3CN)2](ClO4)2: Different mechanisms to form the same Ni(iii) product?†
Abstract
Reaction of [NiII(cyclam)(CH3CN)2](ClO4)2 (1) with
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* Corresponding authors
a
Universidad Autónoma de Madrid, Departamento de Química Inorgánica, Madrid, Spain
E-mail:
ruben.mas@uam.es
Fax: +34914974833
Tel: +34914972947
b
Universitat Autònoma de Barcelona, Departament de Química, Facultat de Ciencies, Bellaterra, Spain
E-mail:
xavi@klingon.uab.es
Fax: +34935812920
Tel: +34935812173
c Instituto de Catálisis y Petroleoquímica (CSIC), Marie Curie 2, Cantoblanco, Madrid, Spain
d Universidad Autónoma de Madrid, Departamento de Química Física Aplicada, Facultad de Ciencias, Madrid, Spain
Reaction of [NiII(cyclam)(CH3CN)2](ClO4)2 (1) with
X. Solans-Monfort, J. L. G. Fierro, L. Hermosilla, C. Sieiro, M. Sodupe and R. Mas-Ballesté, Dalton Trans., 2011, 40, 6868 DOI: 10.1039/C0DT01605E
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