Issue 8, 2011
From the journal:

Dalton Transactions

Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex†

Kristen A. Thoresona  and  Kristopher McNeill*b  

* Corresponding authors

a Department of Chemistry, University of Minnesota, Minneapolis, USA

b Department of Environmental Sciences, ETH, Zurich, Switzerland
E-mail: kris.mcneill@env.ethz.ch
Fax: + 41 44 632 14 38
Tel: + 41 44 632 47 55

Abstract

Dechlorination reactions at sp2 C–Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.

Graphical abstract: Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex

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Article information

DOI
https://doi.org/10.1039/C0DT01532F
Article type
Communication
Submitted
04 Nov 2010
Accepted
05 Jan 2011
First published
25 Jan 2011

Dalton Trans., 2011,40, 1646-1648

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Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex

K. A. Thoreson and K. McNeill, Dalton Trans., 2011, 40, 1646 DOI: 10.1039/C0DT01532F

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