Issue 9, 2011
From the journal:

Dalton Transactions

Si–H Activation of hydrosilanes leading to hydrido silyl and bis(silyl) nickel complexes†‡

Thomas Zell,a   Thomas Schaub,a   Krzysztof Radackia  and  Udo Radius*a  

* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg, Germany
E-mail: u.radius@uni-wuerzburg.de
Fax: +49 931 888 81102
Tel: +49 931 31 80302

Abstract

A general route for the synthesis of novel NHC stabilized nickel bis(silyl) and nickel hydrido silyl complexes is presented. The reaction of [Ni2(iPr2Im)4(COD)] 1 (iPr2Im = 1,3-di-isopropyl-imidazolin-2-ylidene) with hydrosilanes HnSiR4-n leads to complexes of the type [Ni(iPr2Im)2(SiHn-1R4-n)(H)] or [Ni(iPr2Im)2(SiHn-1R4-n)2].

Graphical abstract: Si–H Activation of hydrosilanes leading to hydrido silyl and bis(silyl) nickel complexes

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Article information

DOI
https://doi.org/10.1039/C0DT01442G
Article type
Communication
Submitted
21 Oct 2010
Accepted
20 Dec 2010
First published
18 Jan 2011

Dalton Trans., 2011,40, 1852-1854

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Si–H Activation of hydrosilanes leading to hydrido silyl and bis(silyl) nickel complexes

T. Zell, T. Schaub, K. Radacki and U. Radius, Dalton Trans., 2011, 40, 1852 DOI: 10.1039/C0DT01442G

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