Issue 5, 2011
From the journal:

Dalton Transactions

Tuning emission wavelength and redox properties through position of the substituent in iridium(iii) cyclometallated complexes†

David L. Davies,*a   Mark P. Lowe,a   Karl S. Ryder,a   Kuldip Singha  and  Shalini Singha  

* Corresponding authors

a Department of Chemistry, University of Leicester, Leicester, UK
E-mail: dld3@le.ac.uk
Fax: +44-116-2523789
Tel: +44-116-2092

Abstract

Cyclometallated phenyls with substituents para to the metal have a larger impact on the redox potentials and emission of complexes [Ir(R-ppz)2(bipy)][PF6] than substituents at the meta position and hence enable tuning of emission wavelength over a wider range using the same substituent.

Graphical abstract: Tuning emission wavelength and redox properties through position of the substituent in iridium(iii) cyclometallated complexes

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Article information

DOI
https://doi.org/10.1039/C0DT01311K
Article type
Communication
Submitted
30 Sep 2010
Accepted
23 Nov 2010
First published
21 Dec 2010

Dalton Trans., 2011,40, 1028-1030

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Tuning emission wavelength and redox properties through position of the substituent in iridium(III) cyclometallated complexes

D. L. Davies, M. P. Lowe, K. S. Ryder, K. Singh and S. Singh, Dalton Trans., 2011, 40, 1028 DOI: 10.1039/C0DT01311K

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