New access to (η5-cyclohexadienyl)Mn(CO)3 and cationic (η6-arene)Mn(CO)3 complexes by Suzuki–Miyaura reaction†
Abstract
First Suzuki–Miyaura coupling reactions applied to (η5-chloro-cyclohexadienyl)Mn(CO)3 complexes are described and lead to the syntheses of (η5-aryl-cyclohexadienyl)Mn(CO)3 and of cationic (η6-arene)Mn(CO)3 complexes after rearomatization. The structures of two of the new complexes have been investigated by