Issue 6, 2011

Trinuclear rare earth metal complexes based on 1,3,5-triamino-1,3,5-trideoxy-cis inositol as catalysts for the hydrolysis of phosphodiesters

Abstract

Trinuclear rare-earth metal complexes [M3(taciH−3)2]3+ (M = La3+, Y3+), based on a rigid polyamino–polyalcohol ligand 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (taci), are proven to be efficient catalysts for the hydrolysis of 2-hydroxypropyl-4-nitrophenyl phophate (HPNP), a commonly used RNA model system.

Graphical abstract: Trinuclear rare earth metal complexes based on 1,3,5-triamino-1,3,5-trideoxy-cis inositol as catalysts for the hydrolysis of phosphodiesters

Supplementary files

Article information

Article type
Communication
Submitted
17 Sep 2010
Accepted
03 Dec 2010
First published
06 Jan 2011

Dalton Trans., 2011,40, 1230-1232

Trinuclear rare earth metal complexes based on 1,3,5-triamino-1,3,5-trideoxy-cis inositol as catalysts for the hydrolysis of phosphodiesters

A. M. Ramadan, J. M. Calatayud Sala and T. N. Parac-Vogt, Dalton Trans., 2011, 40, 1230 DOI: 10.1039/C0DT01257B

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