Issue 2, 2011
From the journal:

Dalton Transactions

Linear or cross-shaped di(cyclopentadienyltitanium) compounds with aryl or heteroaryl spacers†

Sana Ahmad,a   Suvendu Sekhar Dey,a   Bernard Jousseaume*a  and  Thierry Toupancea  

* Corresponding authors

a Université de Bordeaux, CNRS, UMR 5255; ISM; Matériaux, 351 cours de la Libération, Talence, France
E-mail: b.jousseaume@ism.u-bordeaux1.fr

Abstract

The preparation of hexamethylated and hexabenzylated arylene or heteroarylene bridged dinuclear di(cyclopentadienyltitanium) compounds from the reaction of the corresponding hexachlorides with methyllithium or benzylmagnesium chloride is described. The spacers between the cyclopentadienyl rings consist of one, two or three phenylene groups, a dioctyloxyphenylene group or a 2,2′-bithienylene group. The corresponding hexachlorides and hexaisopropoxides have also been prepared.

Graphical abstract: Linear or cross-shaped di(cyclopentadienyltitanium) compounds with aryl or heteroaryl spacers

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Article information

DOI
https://doi.org/10.1039/C0DT01060J
Article type
Paper
Submitted
18 Aug 2010
Accepted
28 Sep 2010
First published
15 Nov 2010

Dalton Trans., 2011,40, 457-462

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Linear or cross-shaped di(cyclopentadienyltitanium) compounds with aryl or heteroaryl spacers

S. Ahmad, S. S. Dey, B. Jousseaume and T. Toupance, Dalton Trans., 2011, 40, 457 DOI: 10.1039/C0DT01060J

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