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Issue 9, 2011
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Selective hydrogenation of functionalized nitroarenes under mild conditions

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Abstract

Functionalized anilines are selectively synthesized from the corresponding nitroarenes by simple heterogeneous catalytic hydrogenation carried out under mild conditions over a very low amount (0.5 mol%) of a new sol–gel entrapped Pd(0) catalyst. Only halo-nitroarenes could not be selectively converted. The catalyst is leach-proof and can be reused in many consecutive reaction cycles.

Graphical abstract: Selective hydrogenation of functionalized nitroarenes under mild conditions

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Publication details

The article was received on 18 Mar 2011, accepted on 13 May 2011 and first published on 08 Jun 2011


Article type: Paper
DOI: 10.1039/C1CY00097G
Citation: Catal. Sci. Technol., 2011,1, 1616-1623
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    Selective hydrogenation of functionalized nitroarenes under mild conditions

    V. Pandarus, R. Ciriminna, F. Béland and M. Pagliaro, Catal. Sci. Technol., 2011, 1, 1616
    DOI: 10.1039/C1CY00097G

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