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Issue 3, 2011
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Amine influence in vanadium-based ethylene polymerisation pro-catalysts bearing bis(phenolate) ligands with ‘pendant’ arms

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Abstract

Two families of vanadium complexes bearing diphenolate ligands with different ‘pendant’ arms have been screened under various conditions for the polymerisation behaviour of ethylene. The presence of a bound amine arm was found to favour enhanced thermal stability.

Graphical abstract: Amine influence in vanadium-based ethylene polymerisation pro-catalysts bearing bis(phenolate) ligands with ‘pendant’ arms

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Publication details

The article was received on 14 Mar 2011, accepted on 29 Mar 2011 and first published on 15 Apr 2011


Article type: Paper
DOI: 10.1039/C1CY00089F
Citation: Catal. Sci. Technol., 2011,1, 489-494
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    Amine influence in vanadium-based ethylene polymerisation pro-catalysts bearing bis(phenolate) ligands with ‘pendant’ arms

    C. Lorber, E. Despagnet-Ayoub, L. Vendier, A. Arbaoui and C. Redshaw, Catal. Sci. Technol., 2011, 1, 489
    DOI: 10.1039/C1CY00089F

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