Issue 1, 2011
From the journal:

Catalysis Science & Technology

Rhodium-catalyzed asymmetric phenylation of N-phosphinoylarylimines with triphenylborane†‡

Xinyu Hao,a   Qian Chen,b   Masami Kuriyama,a   Ken-ichi Yamada,a   Yasutomo Yamamotoc  and  Kiyoshi Tomioka*c  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: yamak@pharm.kyoto-u.ac.jp
Fax: +81 75 753 4604
Tel: +81 75 753 4573

b The Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin, Heilongjiang, P. R. China
E-mail: chenqian1jp@yahoo.co.jp

c Faculty of Pharmaceutical Sciences, Doshisha Women's College of Liberal Arts, Kodo, Kyotanabe 610-0395, Japan
E-mail: tomioka@pharm.kyoto-u.ac.jp
Fax: +81 774 65 8658
Tel: +81 774 65 8676

Abstract

Triphenylborane asymmetrically transfers its phenyl group to N-diphenylphosphinoylarylimines to give diarylmethylamines with high ee in high yield without imine hydrolysis under the catalysis of a chiral amidomonophosphane–rhodium(I) complex.

Graphical abstract: Rhodium-catalyzed asymmetric phenylation of N-phosphinoylarylimines with triphenylborane

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Article information

DOI
https://doi.org/10.1039/C0CY00083C
Article type
Communication
Submitted
11 Dec 2010
Accepted
22 Dec 2010
First published
04 Feb 2011

Catal. Sci. Technol., 2011,1, 62-64

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Rhodium-catalyzed asymmetric phenylation of N-phosphinoylarylimines with triphenylborane

X. Hao, Q. Chen, M. Kuriyama, K. Yamada, Y. Yamamoto and K. Tomioka, Catal. Sci. Technol., 2011, 1, 62 DOI: 10.1039/C0CY00083C

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