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Issue 45, 2011
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Conformer interconversion in a switchable porous organic cage

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Abstract

Porous organic cage crystals can show unique properties, such as switching from being porous to non-porous in the solid state. Conformer interconversion plays a crucial role in this for the imine cage molecule, CC1. The barriers to interconversion were calculated and found to match experimentally determined values. Calculations suggest that solvent interactions reduce these activation barriers.

Graphical abstract: Conformer interconversion in a switchable porous organic cage

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Article information


Submitted
05 Aug 2011
Accepted
23 Sep 2011
First published
14 Oct 2011

Phys. Chem. Chem. Phys., 2011,13, 20081-20085
Article type
Communication

Conformer interconversion in a switchable porous organic cage

K. E. Jelfs, F. Schiffmann, J. T. A. Jones, B. Slater, F. Cora and A. I. Cooper, Phys. Chem. Chem. Phys., 2011, 13, 20081
DOI: 10.1039/C1CP22527H

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