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Issue 25, 2011
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Nature of anion-templated π+–π+ interactions

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Abstract

Interaction between positively charged aromatic groups (π+–π+) is characterized by anti-parallel, displaced-stacked structures in the presence of counteranions. Binding energies of pyridinium, N-methylpyridinium and N-methylimidazolium dimers are much larger than that of benzenepyridine (π–π) and pyridinium–benzene+–π). Stabilization is attributed to attractive electrostatic interaction with significant dispersion contribution.

Graphical abstract: Nature of anion-templated π+–π+ interactions

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Article information


Submitted
09 Feb 2011
Accepted
06 May 2011
First published
31 May 2011

Phys. Chem. Chem. Phys., 2011,13, 11841-11845
Article type
Communication

Nature of anion-templated π+–π+ interactions

I. Geronimo, N. Jiten Singh and K. S. Kim, Phys. Chem. Chem. Phys., 2011, 13, 11841
DOI: 10.1039/C1CP20348G

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