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Issue 17, 2011
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Enhanced phosphorescence in dibenzophosphole chalcogenide mixed crystal

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Abstract

The single crystals of 9-phenyl-9-dibenzophosphole chalcogenides {oxide (1), sulfide (2) and selenide (3)} and a mixed crystal of 2 and 3 have been prepared and characterized by X-ray diffraction analysis. Several intermolecular interactions such as π–π and Se–H were observed in the mixed crystal of 2 and 3. The mixed crystal of 2 and 3 exhibited enhanced phosphorescence compared to the pure constituent crystal (2 or 3) at low temperature.

Graphical abstract: Enhanced phosphorescence in dibenzophosphole chalcogenide mixed crystal

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Article information


Submitted
31 Mar 2011
Accepted
02 Jun 2011
First published
05 Jul 2011

CrystEngComm, 2011,13, 5423-5427
Article type
Paper

Enhanced phosphorescence in dibenzophosphole chalcogenide mixed crystal

R. Kabe, V. M. Lynch and P. Anzenbacher Jr., CrystEngComm, 2011, 13, 5423
DOI: 10.1039/C1CE05388D

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